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期刊论文 1407

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Application of fuzzy analytic hierarchy process model on determination of optimized pile-type

Lei MA, Shuilong SHEN, Jinhui ZHANG, Yang HUANG, Feng SHI

《结构与土木工程前沿(英文)》 2010年 第4卷 第2期   页码 252-257 doi: 10.1007/s11709-010-0017-2

摘要: Pile-type selection is a very important stage of foundation design, and there are many field factors influencing the decision of pile-type selection. Since there is a limitation of traditional “major factors method” to satisfy the requirement of modern foundation construction, this study presents an efficient approach, in which analytic hierarchy process (AHP) is employed. AHP is a multiple criteria decision-making tool that has been applied in many fields related to the decision-making, e.g., in the field of economics, marketing, sociology, etc. However, it is rarely reported that AHP is applied in the field of civil engineering for decision making. In this study, AHP combined with fuzzy synthetic evaluation method is employed to select the type of pile used as the foundation of a residential building in Fuzhou, Fujian Province, China. The results show that fuzzy AHP approach is an easy and efficient way for pile-type selection.

关键词: pile type     fuzzy synthetic evaluation     analytic hierarchy process (AHP)     optimal selection    

Non-equilibrium model for catalytic distillation process

WANG Feng, ZHAO Ning, LI Junping, XIAO Fukui, WEI Wei, SUN Yuhan

《化学科学与工程前沿(英文)》 2008年 第2卷 第4期   页码 379-384 doi: 10.1007/s11705-008-0071-7

摘要: A new improved tri-diagonal method was developed for the non-equilibrium stage model of the catalytic distillation by coupling consumptive reaction coefficient. The reactions in the distillation column were divided into generative reaction and consumptive reaction. The non-equilibrium stage model was introduced for the catalytic distillation process of the dimethyl carbonate (DMC) synthesis by urea methanolysis over solid based catalyst, and the improved tri-diagonal method was used to solve the model equations. Comparison of predicted results with experiment data shows that the mean relative error of the yield of DMC was 3.78% under different conditions such as different operating pressures and reaction temperatures. The improved tri-diagonal matrix method could avoid the negative values of the liquid compositions during the calculations and restrain the fluctuation of compositions by slowing down the variations of the values in the iteration. The modeling results show that the improved tri-diagonal method was appropriate for system containing a wide range of boiling point components and a different rate of reactions.

Diffusion process in enzyme–metal hybrid catalysts

《化学科学与工程前沿(英文)》 2022年 第16卷 第6期   页码 921-929 doi: 10.1007/s11705-022-2144-4

摘要: Enzyme–metal hybrid catalysts bridge the gap between enzymatic and heterogeneous catalysis, which is significant for expanding biocatalysis to a broader scope. Previous studies have demonstrated that the enzyme–metal hybrid catalysts exhibited considerably higher catalytic efficiency in cascade reactions, compared with that of the combination of separated enzyme and metal catalysts. However, the precise mechanism of this phenomenon remains unclear. Here, we investigated the diffusion process in enzyme–metal hybrid catalysts using Pd/lipase-Pluronic conjugates and the combination of immobilized lipase (Novozyme 435) and Pd/C as models. With reference to experimental data in previous studies, the Weisz–Prater parameter and efficiency factor of internal diffusion were calculated to evaluate the internal diffusion limitations in these catalysts. Thereafter, a kinetic model was developed and fitted to describe the proximity effect in hybrid catalysts. Results indicated that the enhanced catalytic efficiency of hybrid catalysts may arise from the decreased internal diffusion limitation, size effect of Pd clusters and proximity of the enzyme and metal active sites, which provides a theoretical foundation for the rational design of enzyme–metal hybrid catalysts.

关键词: enzyme–metal hybrid catalyst     internal diffusion     proximity effect     kinetic model    

Theory and method of mechanism system design

Huijun ZOU, Qinghua LIANG, Qing ZHANG

《机械工程前沿(英文)》 2010年 第5卷 第4期   页码 399-411 doi: 10.1007/s11465-010-0116-8

摘要: Conceptual design is the most critical and creative phase of design. Recently, increasing attention has been directed to supporting conceptual-level computer aided creative design and its theories and methodologies. Specifically, for conceptual design of mechanical products, this paper presents a novel function solving model for mechanical product design and highlights the importance of systematic synthesis to achieve creative design. Then it builds a framework as a function-effect-process-action- mechanisms (FEPAM) mapping process, which enables creative design on the basis of conceiving different action schemes. After that, several key points are elaborated including 1) representing and decomposition methods of functions and motion behaviors; 2) action scheme representing method based on network plan techniques; and 3) variation and creation methods based on action scheme transformations.

关键词: mechanism system creative design     process model     function solving model     process action procedure     mechanisms knowledge base     principle of mechanism system composition    

Simple model of sludge thickening process in secondary settlers

Yuankai ZHANG,Hongchen WANG,Lu QI,Guohua LIU,Zhijiang HE,Songzhu JIANG

《环境科学与工程前沿(英文)》 2016年 第10卷 第2期   页码 319-326 doi: 10.1007/s11783-014-0758-6

摘要: In wastewater treatment plants (WWTPs), a secondary settler acts as a clarifier, sludge thickener, and sludge storage tank during peak flows and therefore plays an important role in the performance of the activated sludge process. Sludge thickening occurs in the lower portions of secondary clarifiers during their operation. In this study, by detecting the hindered zone from the complete thickening process of activated sludge, a simple model for the sludge thickening velocity, , describing the potential and performance of activated sludge thickening in the hindered zone was developed. However, sludge thickening in the compression zone was not studied because sludge in the compression zone showed limited thickening. This empirical model was developed using batch settling data obtained from four WWTPs and validated using measured data from a fifth WWTP to better study sludge thickening. To explore different sludge settling and thickening mechanisms, the curves of sludge thickening and sludge settling were compared. Finally, it was found that several factors including temperature, stirring, initial depth, and polymer conditioning can lead to highly concentrated return sludge and biomass in a biologic reactor.

关键词: wastewater treatment plants     secondary settler     sludge thickening     sludge settling     hindered zone    

Catalytic process modeling and sensitivity analysis of alkylation of benzene with ethanol over MIL-101

Ehsan Rahmani, Mohammad Rahmani

《化学科学与工程前沿(英文)》 2020年 第14卷 第6期   页码 1100-1111 doi: 10.1007/s11705-019-1891-3

摘要: A solvothermal method was used to synthesize MIL-101(Fe) and MIL-88(Fe), which were used for alkylation of benzene. The synthesized catalysts were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, field emission scanning electron microscope, dynamic light scattering, and BET techniques. Metal-organic frameworks (MOFs) were modeled to investigate the catalytic performance and existence of mass transfer limitations. Calculated effectiveness factors revealed absence of internal and external mass transfer. Sensitivity analysis revealed best operating conditions over MIL-101 at 120°C and 5 bar and over MIL-88 at 142°C and 9 bar.

关键词: MOFs     alkylation     ethylbenzene     catalysts pellet model     kinetic model     sensitivity analysis    

Decision support for the development, simulation and optimization of dynamic process models

Norbert Asprion, Roger Böttcher, Jan Schwientek, Johannes Höller, Patrick Schwartz, Charlie Vanaret, Michael Bortz

《化学科学与工程前沿(英文)》 2022年 第16卷 第2期   页码 210-220 doi: 10.1007/s11705-021-2046-x

摘要: Simulation is besides experimentation the major method for designing, analyzing and optimizing chemical processes. The ability of simulations to reflect real process behavior strongly depends on model quality. Validation and adaption of process models are usually based on available plant data. Using such a model in various simulation and optimization studies can support the process designer in his task. Beneath steady state models there is also a growing demand for dynamic models either to adapt faster to changing conditions or to reflect batch operation. In this contribution challenges of extending an existing decision support framework for steady state models to dynamic models will be discussed and the resulting opportunities will be demonstrated for distillation and reactor examples.

关键词: decision support     multicriteria optimization     model validation     dynamic model     sensitivity analysis    

动态热过程分析用建筑几何模型的构建

丁力行,何立群,陈祖铭,刘仙萍,季杰

《中国工程科学》 2010年 第12卷 第8期   页码 88-93

摘要:

建筑墙体表面的太阳直射辐射投影及辐射强度随时间发生很大变化,该变化在已有的动态热过程算法框架内很难直接计算。根据建筑传热模型特点和计算机图形学原理,构建了动态热过程的建筑几何模型,该模型将建筑空间抽象为由矢量平面围成的空间区域的集合;提出了建筑几何模型的核心计算方法,即三维空间内直线与表面的矢量运算。该建筑几何模型能解决建筑动态热过程中直接计算建筑墙体表面之间的太阳直射辐射换热和太阳直射辐射投影等问题,并对空气流通、楼房之间的相互遮阳和光污染等问题的研究也具有实际意义。

关键词: 建筑热过程     几何模型     太阳辐射    

Progress in membrane distillation crystallization: Process models, crystallization control and innovative

Xiaobin Jiang, Linghan Tuo, Dapeng Lu, Baohong Hou, Wei Chen, Gaohong He

《化学科学与工程前沿(英文)》 2017年 第11卷 第4期   页码 647-662 doi: 10.1007/s11705-017-1649-8

摘要: Membrane distillation crystallization (MDC) is a promising hybrid separation process that has been applied to seawater desalination, brine treatment and wastewater recovery. In recent years, great progress has been made in MDC technologies including the promotion of nucleation and better control of crystallization and crystal size distribution. These advances are useful for the accurate control of the degree of supersaturation and for the control of the nucleation kinetic processes. This review focuses on the development of MDC process models and on crystallization control strategies. In addition, the most important innovative applications of MDC in the last five years in crystal engineering and pharmaceutical manufacturing are summarized.

关键词: membrane distillation crystallization     mathematics model     nucleation     separation     hybrid process    

prediction method for remaining useful life of lithium-ion batteries based on a neural network and Gaussian process

《能源前沿(英文)》 doi: 10.1007/s11708-023-0906-4

摘要: Lithium-ion batteries (LIBs) are widely used in transportation, energy storage, and other fields. The prediction of the remaining useful life (RUL) of lithium batteries not only provides a reference for health management but also serves as a basis for assessing the residual value of the battery. In order to improve the prediction accuracy of the RUL of LIBs, a two-phase RUL early prediction method combining neural network and Gaussian process regression (GPR) is proposed. In the initial phase, the features related to the capacity degradation of LIBs are utilized to train the neural network model, which is used to predict the initial cycle lifetime of 124 LIBs. The Pearson coefficient’s two most significant characteristic factors and the predicted normalized lifetime form a 3D space. The Euclidean distance between the test dataset and each cell in the training dataset and validation dataset is calculated, and the shortest distance is considered to have a similar degradation pattern, which is used to determine the initial Dual Exponential Model (DEM). In the second phase, GPR uses the DEM as the initial parameter to predict each test set’s early RUL (ERUL). By testing four batteries under different working conditions, the RMSE of all capacity estimation is less than 1.2%, and the accuracy percentage (AP) of remaining life prediction is more than 98%. Experiments show that the method does not need human intervention and has high prediction accuracy.

关键词: lithium-ion batteries     RUL prediction     double exponential model     neural network     Gaussian process regression (GPR)    

基于状态空间法的铁路建设工程过程质量模型研究

鲁守东,周国华,陈海峰,赵国堂

《中国工程科学》 2014年 第16卷 第3期   页码 64-69

摘要:

在ISO9000过程“输入-输出”模型下,过程质量概念很难得到正确的阐释。从过程的“白箱”理论出发,以铁路建设工程的基本作业单元6M1E为例,给出了过程质量概念的科学涵义及过程质量模型。指出基本作业单元系统的过程包括工艺自然过程、作业过程、管理过程;基本作业单元系统的过程质量取决于3个子过程之间的相互联系和相互作用,同时还受到外界扰动输入因素的影响。最后以现浇预应力砼连续箱梁施工过程为例,阐述了该理论在铁路建设工程质量管理中的具体应用。

关键词: 铁路建设工程     “白箱”模型     状态转移方程     过程质量    

Investigation of carbon dioxide photoreduction process in a laboratory-scale photoreactor by computational

《化学科学与工程前沿(英文)》 2022年 第16卷 第7期   页码 1149-1163 doi: 10.1007/s11705-021-2096-0

摘要: The production of solar fuels via the photoreduction of carbon dioxide to methane by titanium oxide is a promising process to control greenhouse gas emissions and provide alternative renewable fuels. Although several reaction mechanisms have been proposed, the detailed steps are still ambiguous, and the limiting factors are not well defined. To improve our understanding of the mechanisms of carbon dioxide photoreduction, a multiphysics model was developed using COMSOL. The novelty of this work is the computational fluid dynamic model combined with the novel carbon dioxide photoreduction intrinsic reaction kinetic model, which was built based on three-steps, namely gas adsorption, surface reactions and desorption, while the ultraviolet light intensity distribution was simulated by the Gaussian distribution model and Beer-Lambert model. The carbon dioxide photoreduction process conducted in a laboratory-scale reactor under different carbon dioxide and water moisture partial pressures was then modeled based on the intrinsic kinetic model. It was found that the simulation results for methane, carbon monoxide and hydrogen yield match the experiments in the concentration range of 10−4 mol·m–3 at the low carbon dioxide and water moisture partial pressure. Finally, the factors of adsorption site concentration, adsorption equilibrium constant, ultraviolet light intensity and temperature were evaluated.

关键词: carbon dioxide photoreduction     computational fluid dynamic simulation     kinetic model     Langmuir adsorption    

Exploring price effects on the residential water conservation technology diffusion process: a case study

Junying CHU, Hao WANG, Can WANG

《环境科学与工程前沿(英文)》 2013年 第7卷 第5期   页码 688-698 doi: 10.1007/s11783-013-0559-3

摘要: Reforms of the water pricing management system and the establishment of a flexible water pricing system are significant for cities in northern China to tackle their critical water issues. The WATAP (Water conservation Technology Adoption Processes) model is developed in order to capture the water conservation technology adoption process under different price scenarios with disaggregate water demands down to the end use level. This model is explicitly characterized by the technological selection process under maximum marginal benefit assumption by different categories of households. In particular, when households need to purchase water devices in the provision market with the consideration of complex factors such as the life span, investment and operating costs of the device, as well as the regulated water price by the government. Applied to Tianjin city, four scenarios of water price evolutions for a long-term perspective (from year 2011 to 2030) are considered, including BAU (Business As Usual), SP1 (Scenario of Price increase with constant annual rate), SP2 (Scenario of Price increase every four years) and SP3 (Scenario of Price increase with affordable constraint), considering many factors such as historic trends, affordability and incentives for conservation. Results show that on aggregate 2.3%, 11.0% and 18.2% of fresh water can be saved in the residential sector in scenario SP1, SP2 and SP3, respectively, compared with the BAU scenario in the year 2030. The water price signals can change the market shares of different water appliances, as well as the water end use structure of households, and ultimately improve water use efficiency. The WATAP model may potentially be a helpful tool to provide insights for policy makers on water conservation technology policy analysis and assessment.

关键词: technology selection     model optimization     water price     scenario analysis     consumer behavior    

知识创新随机过程最大熵模型

陈欣,和金生,董丽平

《中国工程科学》 2004年 第6卷 第12期   页码 43-46

摘要:

根据创新知识的形成受已有相关知识影响的假设,综合运用概率统计、最优化、最大熵原理构建了知识创新随机过程最大熵模型,给出了以已有知识x∈X为约束的新知识y∈Y的条件概率p(y|x)。模型具有随机性与因果性对立统一的特点。

关键词: 最大熵     知识创新     条件熵     随机过程    

流程工业智能制造展望:过程系统工程师面临的挑战

Lockhart Bogle Ian David

《工程(英文)》 2017年 第3卷 第2期   页码 161-165 doi: 10.1016/J.ENG.2017.02.003

摘要:

本文讨论了流程工业智能制造对过程系统工程(PSE) 研究人员提出的挑战。现有的研究在实现全厂和全站点优化方面已经取得了很大进展,进行基准化测试能够增加说服力。本文进一步讨论了过程系统工程师在开发可用工具和技术时遇到的技术性挑战,包括灵活性和不确定性,响应性和敏捷性,鲁棒性和安全性,混合物性质和功能的预测,以及新的建模和数学范式。利用大数据进行智能化开发来驱动系统灵活性需要面对新的挑战,例如,如何在漫长又复杂的供应链中确保数据的一致性和机密性。建模方面也存在很多挑战,涉及如何对所有的关键技术进行恰当的建模,特别是健康、安全和环境方面,需要在特定地点对微小却关键的量进行准确预测。对环境方面的关注要求我们紧密跟踪所有的分子种类,以便于它们能被最佳地用于创造可持续的解决方案。而源自于新型个性化产品的破坏性商业模式对环境的影响则难以预测。

关键词: 智能制造     过程系统工程     不确定性     灵活性     优化     基于模型的控制    

标题 作者 时间 类型 操作

Application of fuzzy analytic hierarchy process model on determination of optimized pile-type

Lei MA, Shuilong SHEN, Jinhui ZHANG, Yang HUANG, Feng SHI

期刊论文

Non-equilibrium model for catalytic distillation process

WANG Feng, ZHAO Ning, LI Junping, XIAO Fukui, WEI Wei, SUN Yuhan

期刊论文

Diffusion process in enzyme–metal hybrid catalysts

期刊论文

Theory and method of mechanism system design

Huijun ZOU, Qinghua LIANG, Qing ZHANG

期刊论文

Simple model of sludge thickening process in secondary settlers

Yuankai ZHANG,Hongchen WANG,Lu QI,Guohua LIU,Zhijiang HE,Songzhu JIANG

期刊论文

Catalytic process modeling and sensitivity analysis of alkylation of benzene with ethanol over MIL-101

Ehsan Rahmani, Mohammad Rahmani

期刊论文

Decision support for the development, simulation and optimization of dynamic process models

Norbert Asprion, Roger Böttcher, Jan Schwientek, Johannes Höller, Patrick Schwartz, Charlie Vanaret, Michael Bortz

期刊论文

动态热过程分析用建筑几何模型的构建

丁力行,何立群,陈祖铭,刘仙萍,季杰

期刊论文

Progress in membrane distillation crystallization: Process models, crystallization control and innovative

Xiaobin Jiang, Linghan Tuo, Dapeng Lu, Baohong Hou, Wei Chen, Gaohong He

期刊论文

prediction method for remaining useful life of lithium-ion batteries based on a neural network and Gaussian process

期刊论文

基于状态空间法的铁路建设工程过程质量模型研究

鲁守东,周国华,陈海峰,赵国堂

期刊论文

Investigation of carbon dioxide photoreduction process in a laboratory-scale photoreactor by computational

期刊论文

Exploring price effects on the residential water conservation technology diffusion process: a case study

Junying CHU, Hao WANG, Can WANG

期刊论文

知识创新随机过程最大熵模型

陈欣,和金生,董丽平

期刊论文

流程工业智能制造展望:过程系统工程师面临的挑战

Lockhart Bogle Ian David

期刊论文